Öz
Kaynakça
- Angeli, E., Wagner, J., Lawrick, E., Moore, K., Anderson, M., Soderland, L., & Brizee, A. (2010, May 5). General format. Retrieved from http://owl.english.purdue.edu/owl/resource/560/01/ Calfee, R. C., & Valencia, R. R. (1991). APA guide to preparing manuscripts for journal publication. Washington, DC: American Psychological Association. Duncan, G. J., & Brooks-Gunn, J. (Eds.). (1997). Consequences of growing up poor. New York, NY: Russell Sage Foundation. Harlow, H. F. (1983). Fundamentals for preparing psychology journal articles. Journal of Comparative and Physiological Psychology, 55, 893-896. Helfer, M. E., Kempe, R. S., & Krugman, R. D. (1997). The battered child (5th ed.). Chicago, IL: University of Chicago Press. Henry, W. A., III. (1990, April 9). Making the grade in today's schools. Time, 135, 28-31. Lastname, F. N. (Year). Title of dissertation. (Doctoral dissertation). Retrieved from Name of database. (Accession or Order Number) Lastname, F. N. (Year). Title of dissertation. (Unpublished doctoral dissertation). Name of Institution, Location. O'Neil, J. M., & Egan, J. (1992). Men's and women's gender role journeys: A metaphor for healing, transition, and transformation. In B. R. Wainrib (Ed.), Gender issues across the life cycle (pp. 107-123). New York, NY: Springer. Plath, S. (2000). The unabridged journals. K. V. Kukil (Ed.). New York, NY: Anchor. Schnase, J. L., & Cunnius, E. L. (Eds.). (1995). Proceedings from CSCL '95: The First International Conference on Computer Support for Collaborative Learning. Mahwah, NJ: Erlbaum. Schultz, S. (2005, December 28). Calls made to strengthen state energy policies. The Country Today, pp. 1A, 2A. Scruton, R. (1996). The eclipse of listening. The New Criterion, 15(30), 5-13.
Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide
Öz
The work presented in research describes the preparation and characterization of new complexes resulted from the reaction of diaminothiuramdisulfide(tds)with metals (or metals chlorides)of group(VIII)[Na2pdcl4,Pt(0) and K2ptcl4]in addition to group(IB)metals[Ag(0) ,AgCl and Au(o)]. The thiuramdisulfide compound (tds) reduced to the corresponding aminodithiocarbamate anion (H2NNHCS2)-in some complexes(Oxidative addition reaction ) However, in the remaining complexes the (tds)were simply added to the metal chloride ( addition reaction) without cleavage of the –S-S-bond.the resulting complexes can be classified as follows.
I-The oxidative addition reactions offered complexes of the type:
1-[M(L)2]((Where L=H2NNHCS2-(aminodithiocarbamate anion) and M=Pd(II),Pt(II) , Ag(II ))and [Ag2(L)4NiCl2].
2-[M(L)3][M=Au(III)]in addition to the complexes
[Au(L)3(1,10 –Phen)] .
II-The addition reactions resulted in the formation of the complexes [M(tds)Cl2] whene Pt(II).The prepared complexes were characterized using molar conductivity, UV-Vis and IR spectra in addition to magnetic measurements and metal analysis by atomic absorption .The results suggest a tetra-or hexa-coordinated complexes and also displayed the importance of using different solvents upon the type of reaction and prodect.
Anahtar Kelimeler
Kaynakça
- Angeli, E., Wagner, J., Lawrick, E., Moore, K., Anderson, M., Soderland, L., & Brizee, A. (2010, May 5). General format. Retrieved from http://owl.english.purdue.edu/owl/resource/560/01/ Calfee, R. C., & Valencia, R. R. (1991). APA guide to preparing manuscripts for journal publication. Washington, DC: American Psychological Association. Duncan, G. J., & Brooks-Gunn, J. (Eds.). (1997). Consequences of growing up poor. New York, NY: Russell Sage Foundation. Harlow, H. F. (1983). Fundamentals for preparing psychology journal articles. Journal of Comparative and Physiological Psychology, 55, 893-896. Helfer, M. E., Kempe, R. S., & Krugman, R. D. (1997). The battered child (5th ed.). Chicago, IL: University of Chicago Press. Henry, W. A., III. (1990, April 9). Making the grade in today's schools. Time, 135, 28-31. Lastname, F. N. (Year). Title of dissertation. (Doctoral dissertation). Retrieved from Name of database. (Accession or Order Number) Lastname, F. N. (Year). Title of dissertation. (Unpublished doctoral dissertation). Name of Institution, Location. O'Neil, J. M., & Egan, J. (1992). Men's and women's gender role journeys: A metaphor for healing, transition, and transformation. In B. R. Wainrib (Ed.), Gender issues across the life cycle (pp. 107-123). New York, NY: Springer. Plath, S. (2000). The unabridged journals. K. V. Kukil (Ed.). New York, NY: Anchor. Schnase, J. L., & Cunnius, E. L. (Eds.). (1995). Proceedings from CSCL '95: The First International Conference on Computer Support for Collaborative Learning. Mahwah, NJ: Erlbaum. Schultz, S. (2005, December 28). Calls made to strengthen state energy policies. The Country Today, pp. 1A, 2A. Scruton, R. (1996). The eclipse of listening. The New Criterion, 15(30), 5-13.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Konular | Mühendislik |
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 24 Kasım 2019 |
| Yayımlandığı Sayı | Yıl 2019Cilt: 7 |
