Synthesis and Characterization of Zeolite Templated Carbon and Usage as Adsorbent for Removal of Pb(II) Ions from Solution

Fatma Tumsek

Research Article

Synthesis and Characterization of Zeolite Templated Carbon and Usage as Adsorbent for Removal of Pb(II) Ions from Solution

Year 2018, Issue: 4, 87 - 93, 04.12.2018

Fatma Tumsek

Abstract

In
this study, the porous carbon was prepared through templated synthesis method
using the natural zeolite as template and sugar as carbon source. The porous
carbon was obtained at a carbonization temperature of 700^oC with a
weight ratio 1:1 for zeolite and sugar. The physical, structural and surface
properties of the porous carbon were characterized with the scanning electron
microscope (SEM), transmission electron microscope (TEM), X-ray diffraction
(XRD), elemental analysis and nitrogen (N₂) adsorption. The specific
surface area and total pore volume of carbon were found as 412 m²/g
and 0.5515 cm³/g, respectively. This carbon material was used for
removal of Pb²⁺ ions from solution. The effects of initial pH, temperature
and contact time on adsorption were studied. The maximum Pb²⁺
removal was observed at pH=5. The adsorption was reached to the equilibrium in
120 minutes. Various kinetic models were used for describing the adsorption
kinetic and the pseudo-second order kinetic model showed well fit. Langmuir,
Freundlich and Temkin isotherm models were applied to the experimental
equilibrium data and Langmuir equation was found as best fitting isotherm.

Keywords

Templated carbon , Characterization , Adsorption , Lead

References

Bakandritsos, A., Kouvelos E., Streostis, Th., Petridis, D. (2004). Aqueous and gaseous adsorption from montmorillonite–carbon composites and from derived carbons. Langmuir, 21, 2349. Barata-Rodrigues, P.M., Mays, T.J., &Moggridge, G.D. (2003). S Structured carbon adsorbents from clay, zeolite and mesoporous aluminosilicate templates. Carbon, 41, 2231–2246. Barczak, M., Michalak-Zwierz, K., Gdula, K., Tyszczuk-Rotko, K., Dobrowolski, R., Dabrowski, A. (2015). Ordered mesoporous carbons as effective sorbents for removal of heavy metal ions. Microporous and Mesoporous Materials, 211, 162-173. Böhme, K., Einicke, W.D., &Kepel, O. (2005). Templated synthesis of mesoporous carbon from sucrose-the way from the silica pore filling to the carbon material. Carbon, 43, 1918-1925. Ma, Y.X., Kou, Y.L., Xing, D., Jin, P.S., Shao, W.J., Li, X., Du, X.Y., &La., P.Q. (2017). Synthesis of magnetic graphene oxide grafted polymaleicamide dendrimer nanohybrids for adsorption of Pb(II) in aqueous solution. Journal of Hazardous Materials, 340, 407-416. Pawar, R.R., Lalhmunsiama, Kim, M., Kim, J.G., Hong, S.M., Sawant, S.Y., &Lee, S.M. (2018). Efficient removal of hazardous lead, cadmium, and arsenic from aqueous environment by iron oxide modified clay-activated carbon composite beads. Applied Clay Science, 162, 339-350. Sakintuna, B., &Yürüm, Y. (2006). Preparation and characterization of mesoporous carbons using a Turkish natural zeolitic template/furfuryl alcohol system, Microporous and Mesoporous Materials, 93, 304-312. Santos, C., Andrade, M., Vieira, A.L., Martins, A., Pires, J., Freire, C., &Carvalho, A.P. (2010). Templated synthesis of carbon materials mediated by porous clay heterostructures. Carbon, 48, 4049–4056. Sawant, S.Y., Pawar, R.R., Lee, S.M., &Cho, M.H. (2017). Binder-free production od 3D N-doped porous carbon cubes for efficient Pb2+ removal through batch and fixed bed adsorption. Journal of Cleaner Production, 168, 290-301. Tang, N., Niu, C.G., Li, X.T., Liang, C., Guo, H., Lin, L.S., Zheng, C.W., &Zeng, G.M. (2018). Efficient removal of Cd2+ and Pb2+ from aqueous solution with amino- and thiol-functionalized activated carbon: Isotherm and kinetics modeling. Science of the Total Environment, 635, 1331-1344.

Year 2018, Issue: 4, 87 - 93, 04.12.2018

Fatma Tumsek

Abstract

References

Bakandritsos, A., Kouvelos E., Streostis, Th., Petridis, D. (2004). Aqueous and gaseous adsorption from montmorillonite–carbon composites and from derived carbons. Langmuir, 21, 2349. Barata-Rodrigues, P.M., Mays, T.J., &Moggridge, G.D. (2003). S Structured carbon adsorbents from clay, zeolite and mesoporous aluminosilicate templates. Carbon, 41, 2231–2246. Barczak, M., Michalak-Zwierz, K., Gdula, K., Tyszczuk-Rotko, K., Dobrowolski, R., Dabrowski, A. (2015). Ordered mesoporous carbons as effective sorbents for removal of heavy metal ions. Microporous and Mesoporous Materials, 211, 162-173. Böhme, K., Einicke, W.D., &Kepel, O. (2005). Templated synthesis of mesoporous carbon from sucrose-the way from the silica pore filling to the carbon material. Carbon, 43, 1918-1925. Ma, Y.X., Kou, Y.L., Xing, D., Jin, P.S., Shao, W.J., Li, X., Du, X.Y., &La., P.Q. (2017). Synthesis of magnetic graphene oxide grafted polymaleicamide dendrimer nanohybrids for adsorption of Pb(II) in aqueous solution. Journal of Hazardous Materials, 340, 407-416. Pawar, R.R., Lalhmunsiama, Kim, M., Kim, J.G., Hong, S.M., Sawant, S.Y., &Lee, S.M. (2018). Efficient removal of hazardous lead, cadmium, and arsenic from aqueous environment by iron oxide modified clay-activated carbon composite beads. Applied Clay Science, 162, 339-350. Sakintuna, B., &Yürüm, Y. (2006). Preparation and characterization of mesoporous carbons using a Turkish natural zeolitic template/furfuryl alcohol system, Microporous and Mesoporous Materials, 93, 304-312. Santos, C., Andrade, M., Vieira, A.L., Martins, A., Pires, J., Freire, C., &Carvalho, A.P. (2010). Templated synthesis of carbon materials mediated by porous clay heterostructures. Carbon, 48, 4049–4056. Sawant, S.Y., Pawar, R.R., Lee, S.M., &Cho, M.H. (2017). Binder-free production od 3D N-doped porous carbon cubes for efficient Pb2+ removal through batch and fixed bed adsorption. Journal of Cleaner Production, 168, 290-301. Tang, N., Niu, C.G., Li, X.T., Liang, C., Guo, H., Lin, L.S., Zheng, C.W., &Zeng, G.M. (2018). Efficient removal of Cd2+ and Pb2+ from aqueous solution with amino- and thiol-functionalized activated carbon: Isotherm and kinetics modeling. Science of the Total Environment, 635, 1331-1344.

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Details

Primary Language	English
Subjects	Engineering
Journal Section	Articles
Authors	Fatma Tumsek
Publication Date	December 4, 2018
Published in Issue	Year 2018 Issue: 4

Cite

APA	Tumsek, F. (2018). Synthesis and Characterization of Zeolite Templated Carbon and Usage as Adsorbent for Removal of Pb(II) Ions from Solution. The Eurasia Proceedings of Science Technology Engineering and Mathematics(4), 87-93.