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Selective Transport of Bismuth from Heavy Metal Solution by Ionic Liquid-Based Polymer Inclusion Membrane IL-PIM

Year 2025, Volume: 34, 333 - 338, 01.08.2025

Mohamed Malki Rabea Meziani Lynda Mitiche Amar Sahmoune Claudia Fontas

https://doi.org/10.55549/epstem.1755297

Abstract

Bismuth is an important critical metal which is under risk of supply. It is mainly found and
extracted at trace amounts in copper, lead, tin and gold mining by-product. In this work, we present the results
of the selective transport of trace bismuth Bi(III) from a solution of heavy metals by an Ionic liquids-based
Polymer Inclusion Membranes (PIM), using the task-specific ionic liquid: trihexyl(tetradecyl) phosphonium
salicylate (THTDPS), as extractant and ion carrier. The TS-IL was first synthesized by exchanging the inorganic
anion of trihexyl(tetradecyl) phosphonium chloride Cyphos IL 101 with the organic anion of sodium salycilate.
Important parameters influencing extraction and transport have been examined and optimized. The studied PIM
is composed of 50% CTA, and 50% THTDPS without any additional chemical (modifier or plasticizer).
The performance and stability of the PIM was carried out in depth. The selective transport of Bi(III) from
a solution containing the heavy metals: Pb(II), Cu(II), Cd(III), Ni(II) was carried out. The feed phase is
composed of trace concentration of the metal ions (10 mg.L-1
) in 1M HCl. The optimal receiving phase
conditions were studied and the best composition is EDTA 0.05M at pH 5. The PIM exhibits a good selectivity
towards Bi(III), and the transport rates are reported to be 74.8 ± 9% for Bi(III), against 62.23%, 14.8 ± 9%, 3.15
± 3.15%, and 2.5 ± 2.5% for Cd(II), Pb(II), Cu(II), and Ni(II), respectively. The study of the stability shows that
the PIM can be used up to 5 cycles of extraction-back extraction without significant decrease in the efficiency.

Keywords

Ionic liquids Polymer inclusion membranes Metal separation

References

  • Malki, M., Meziani R., Mitiche, L., Sahmoune, A., & Fontas C. (2025). Selective transport of bismuth from heavy metal solution by ionic liquid-based polymer inclusion membrane IL-PIM. The Eurasia Proceedings of Science, Technology, Engineering and Mathematics (EPSTEM), 34, 333-338.
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Details

Primary Language English
Subjects Separation Processes
Journal Section Articles
Authors

Mohamed Malki

Rabea Meziani

Lynda Mitiche

Amar Sahmoune

Claudia Fontas

Early Pub Date August 1, 2025
Publication Date August 1, 2025
Submission Date March 7, 2025
Acceptance Date April 29, 2025
Published in Issue Year 2025 Volume: 34

Cite

APA Malki, M., Meziani, R., Mitiche, L., … Sahmoune, A. (2025). Selective Transport of Bismuth from Heavy Metal Solution by Ionic Liquid-Based Polymer Inclusion Membrane IL-PIM. The Eurasia Proceedings of Science Technology Engineering and Mathematics, 34, 333-338. https://doi.org/10.55549/epstem.1755297
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