Research Article
Year 2019,
Volume: 6 , 43 - 51, 25.07.2019
Abstract
References
- N. H. Pilkington and R. Robson. Aust. J. Chem. 23, 2225-2236 (1970). J. G. Hughes and R. Robson, Inorg. Chim. Acta , 35, 87-92 , (1979) . S. Brooker, Coord. Chem. Rev., 222 , 35-56 , (2001) . C. K. Mckenzie and R. Robson, Inorg. Chem. 26 , 3615 – 3621 , ( 1987 ). A. Christensen , C. Mayer , F. Jensen , A. D. Bond and C. J. Mekenzie , Dalton Trans , 108 – 120 , (2008) . J. D. G. Correia , A. Domingos , I. Santos and H. Spies , J. Chem . Soc. Dalton Trans , 2245 – 2250 , (2001) . T. Kniess , C. Fernandes , I. Santos , W. Kraus and H. Spies , Inorg. Chim. Acta , 348 , 237 – 241 (2003) . S.J. loeb and J.R. Mansfield, Can J. Chem. , 74 , 1377 – 1390 , (1996) . R. M. Olk , B. Olk , W. Dietzsch , R. Kirmse and E. Hoyer , Coord. Chem. Rev. , 117 ,99 , (1992) . P. Cassox , L. Valade , H. Kobayashi , A. Kobayashi , R. A. Clark and A. Underhill , Coord. Chem. Rev, 110 , 115 , (1991) . J. Becher , A. Hazell , C. J. Mekenzie and C. Vestergaard , Polyhedron , 19 , 665 – 672 , (2000) . J. A. W. llis , M. Lutz, A.L. Spek and E. Boaman , J. Chem. Dulton Trans, 1275, (2002). J. A. W. Verhagen, M. Beretta, A. L. Spek and E. Bouwman , Inorg-Chim. Acta , 357 , 2687 – 2693 , (2004) . C. Bing, W. F. F. Tzeng , C. M. Che. , H. Y. Chao, K.K. Cheung and S. M. Peng , J. Chem. Soc. Dalton, Trans. , 1017 , (1999). N. H. Buttrus , E. A. Abdalrazaq and A. K. AL-Sger , Int. J. Chem. Sci: 5(3) , 1111 – 1120 , (2007). N. H. Buttrus , S. N. Mohammed , A. A-Subah and E. Abdalrazaq – Asian J. Chem. 23(a), 4886-4891, (2013). N. H. Buttrus and F.Saeed , Res. J. Chem. Sci. , 2(6) , 43 – 49 , (2012) . W.J. Geary , Coord. Chem. Rev. , 7, 8 , (1971). N. H. Buttrus , A. K. Hussain and T. A. K. AL-Allaf , Asian . Chem. , 15(3) , 1671, (2003). L. J. AL-Hayly , N. H. Buttrus , F. Taraq and T. A. K. AL-Allaf , J.J. Appl. Sci, 17(1), 64-70 , (2005). T. A. K. AL-Allaf , I. A. Mustafa and S. F. AL-Muktar, Transition Met. Chem. , (8) , 1 , (1993). N. H. Buttrus ,Mu'tah J. Res, and Studies 12(3), 225, (1997). N. M. Buttrus , S. A. Ahmed and W. M. Jameel, Res. J. Chem. Sci. , 3(11), 47-54 , (2013). R. G. Mcdonald , M. J. Riley and M. A. Hithman , Inorg . Chem. , 28, 752 , (1989) .
Synthesis and Characterization of some New Dinuclear Complexes of Ni(II), Pd(II) and Pt(II) with Bulky Substituted Thioether Ligands
Abstract
A series of new multidentate ligands (L1-L4), 1,1,2,2-tetrakis [2-(benzylthio)ethylthio]ethylene(L1),1,1,2,2-tetrakis
[2-(o-tolylthio) ethylthio]) ethylene
(L2) , 1,1,2,2-tetrakis
[3-(p-chlorophenylthio) ethylthio] ethylene (L3) and 1,1,2,2-tetrakis [2-(o-aminophenylthio)
ethylthio] ethyene (L4) were prepared
from the reaction of equimolamar amount of (4-mercapto-2-thia-1-butyl benzene
or o-methyl-4-mercapto-1-thia-1-butyl benzene or
p-chloro-4-mercapto-1-thia-1-butyl benzene or o-amino-4-mercapto
-1-thia-1-butyl benzene and KOH) with tetrachloroethylene in (4:4:1) molar ratio
. Reaction of the above ligands with nickel (II) , palladium (II) and platinum (II) chloride salts gave the
complexes of the general formulas : [M2(L)Cl4] and [Ni2(L)Cl2]Cl2 M=Ni(II) ,
Pd(II) and Pt(II) , L=L1-L4 . The synthesized ligands have been characterized
on the basis of their elemental analysis , FTIR, 1H ,13C NMR , and their
complexes were characterized by elemental analysis metal content, UV-Vis. spectroscopic
technique ,conductivity measurements and magnetic measurements. On the basis of
these studies, a four coordinate tetrahedral or square planar geometry around
the metal ions in the complexes has been proposed.
References
- N. H. Pilkington and R. Robson. Aust. J. Chem. 23, 2225-2236 (1970). J. G. Hughes and R. Robson, Inorg. Chim. Acta , 35, 87-92 , (1979) . S. Brooker, Coord. Chem. Rev., 222 , 35-56 , (2001) . C. K. Mckenzie and R. Robson, Inorg. Chem. 26 , 3615 – 3621 , ( 1987 ). A. Christensen , C. Mayer , F. Jensen , A. D. Bond and C. J. Mekenzie , Dalton Trans , 108 – 120 , (2008) . J. D. G. Correia , A. Domingos , I. Santos and H. Spies , J. Chem . Soc. Dalton Trans , 2245 – 2250 , (2001) . T. Kniess , C. Fernandes , I. Santos , W. Kraus and H. Spies , Inorg. Chim. Acta , 348 , 237 – 241 (2003) . S.J. loeb and J.R. Mansfield, Can J. Chem. , 74 , 1377 – 1390 , (1996) . R. M. Olk , B. Olk , W. Dietzsch , R. Kirmse and E. Hoyer , Coord. Chem. Rev. , 117 ,99 , (1992) . P. Cassox , L. Valade , H. Kobayashi , A. Kobayashi , R. A. Clark and A. Underhill , Coord. Chem. Rev, 110 , 115 , (1991) . J. Becher , A. Hazell , C. J. Mekenzie and C. Vestergaard , Polyhedron , 19 , 665 – 672 , (2000) . J. A. W. llis , M. Lutz, A.L. Spek and E. Boaman , J. Chem. Dulton Trans, 1275, (2002). J. A. W. Verhagen, M. Beretta, A. L. Spek and E. Bouwman , Inorg-Chim. Acta , 357 , 2687 – 2693 , (2004) . C. Bing, W. F. F. Tzeng , C. M. Che. , H. Y. Chao, K.K. Cheung and S. M. Peng , J. Chem. Soc. Dalton, Trans. , 1017 , (1999). N. H. Buttrus , E. A. Abdalrazaq and A. K. AL-Sger , Int. J. Chem. Sci: 5(3) , 1111 – 1120 , (2007). N. H. Buttrus , S. N. Mohammed , A. A-Subah and E. Abdalrazaq – Asian J. Chem. 23(a), 4886-4891, (2013). N. H. Buttrus and F.Saeed , Res. J. Chem. Sci. , 2(6) , 43 – 49 , (2012) . W.J. Geary , Coord. Chem. Rev. , 7, 8 , (1971). N. H. Buttrus , A. K. Hussain and T. A. K. AL-Allaf , Asian . Chem. , 15(3) , 1671, (2003). L. J. AL-Hayly , N. H. Buttrus , F. Taraq and T. A. K. AL-Allaf , J.J. Appl. Sci, 17(1), 64-70 , (2005). T. A. K. AL-Allaf , I. A. Mustafa and S. F. AL-Muktar, Transition Met. Chem. , (8) , 1 , (1993). N. H. Buttrus ,Mu'tah J. Res, and Studies 12(3), 225, (1997). N. M. Buttrus , S. A. Ahmed and W. M. Jameel, Res. J. Chem. Sci. , 3(11), 47-54 , (2013). R. G. Mcdonald , M. J. Riley and M. A. Hithman , Inorg . Chem. , 28, 752 , (1989) .
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Details
| Primary Language | English |
|---|---|
| Subjects | Engineering |
| Journal Section | Articles |
| Authors | |
| Publication Date | July 25, 2019 |
| Published in Issue | Year 2019Volume: 6 |
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