Synthesis, Investigation and X-Ray Powder Diffraction (XRD) of Some Oxadiazole Complexes

Amerah Jihad Ahmed Shaheen

Research Article

Synthesis, Investigation and X-Ray Powder Diffraction (XRD) of Some Oxadiazole Complexes

Year 2019, Volume: 6 , 151 - 161, 25.07.2019

Amerah Jihad Ahmed Shaheen

Abstract

New ligand; 2-(1,1-dimethoxymethane) thio-5-
(phenyl)-1,3,4-oxadiazole (L)(3) and its complexes with Mn(II), Fe(III),
Co(II), Ni(II), Cd(II) and Zr(IV), have been synthesized and characterized on
the basis of physicochemical investigations including infrared and electronic
spectroscopy,magnetic moment measurements, molar conductance and elemental
analysis. The structures of the compounds and some complexes have been
investigated by X-ray powder diffraction and H1NMR spectra. was recorded on
broker shield 300 MHz using deutrated DMSO-d6 as a solvent. for ligand. They
have been found to have the formula; [M L (H2O)3Cl]Cln; M= Mn(II ) n = 1, (4)
and M= Fe(III), n = 2 (5),
[ML (H2O) Cl)] Cl , M=. Co(II) (7), Cd(II) (8)and [NiLCl2](6) ,[ZrOL(H2O)
Cl2]Cl2 (9), in molar ratio 1:1. Infrared spectral data suggest that the ligand
L: behaves as a, bidentate ligand with N,S, donor sequence towards the metal
ions. According to the above physicochemical data, octahedral and tetrahedral
geometries were assigned for the complexes.

Keywords

Complexes, Oxadiazole, X-ray studies

References

Kalagudasi G, Manjula P, Ramesh, V., Rashmisheoy and Sidappa P.''(2007), Transition metal complexes with a new tridentate ligand, 5-_6-(5- mercapto-1,3,4 -oxadiazol -2-yl) pyridin -2-yl-1,3,4-oxadiazole-2- thiol", J. Serb. Chem. Soc. 72, ( 4) 357–366. Almasirad, A; Tabatabai, S.A and Faizi, M; (2004) "Synthesis and biological activity of 1,3,4- oxadiazole derivatives"; Biorg. Med. Chem. Lett; 14, pp. 6057,. Abdel Hamid,M; , (2008)" Synthesis and cyclization reactions with oxadiazole dervatives and their enzymaic activity; Acta. Chim. Slov; 55,. 492-501 Bhat, M. A; Siddiqui, N and Khan, S.A; (2008)." Synthesis of novel 3-(4-Acetyl-5H-methyl-5-substituted phenyl-4,5-dihydro-1,3,4-oxadiazol-2-yl)-2H-chromen -2-ones as potential anticonvulsant agent, Polish. Pharm. Soc; 65 , pp.235-239. Shabbir Akazi (2011)", Synthesis and characterization of a new bidentate ligand 5 -substituted-(2- methyl-5 -nitro-1- imidazomethyl) -1,3,4oxadiazole 2-thione and its metal complexes of Ag(I), Cu(II) and Zn(II)", E -J. of Chemistry 8(S1), S127-S136. Najat A.obaidy,K.K.Abid, Yusra, (2006)." Transition metal complexes of 1,3,4-oxadiazole ligands",National J .of Chem.,24,629-641 H.L. Yale, K. Losee, J. Martins, M. Holsing, F.M. Pery and J. Bernstein, (1953), “Chemotherapy of experimental tuberculosis. VIII. The synthesis of acid hydrazides, Their derivatives and related compounds”, J. Am. Chem. Soc., 75, 1933 Yong Wood(1955) ,"The cyclization of 3- acyl dithiocarbazates ester", J.Am.Chem.Soc.,77. Amira Jihad Al- Shaheen, Tamem A . Al- Muhger, ( 2016) " Synthesis, Spectroscopic and X- ray Powder Diffraction(XRD) of Some Oxadiazole Complexes. " International Journal of Enhanced Research in Science ,Technology & Engineering , ISSN :2319-7463 , Vol.5 issue 6 , June-, p.1339. Amira Jihad Al- Shaheen, Mustafa R.A.Al-Bayati and Amal M.A.Abid Allah.,( 2018) "Synthesis and Characterization of some Metals(II) complexes with 2-(6- methoxy naphthalene-2-yl)Propionic acid(2- hydroxyl benzylidene) hydrazine ligand" . International Journal of Enhanced Research in Science ,Technology & Engineering , ISSN :2319-7463 , ISSN: 2319-7463, Vol 7 Issue 4 april-, Impact Factor: 4.059. Geary W.J( 1971).,"The use of conductivity measurement in organic solvent for Characterization of coordination compounds" , Coord. Chem. Rev., 7, 8 Al- Sabaawi S.A. A .J. Al- Shaheen, (2019)., "Preparation and Physicochemica l Investigation of Manganese (II) complexes with Hydrazone Ligands.,Raf .J .Sc.,Vol .28 ,No.2, Specia l Issue for third Scientific Conference of Chemistry pp.204-210. Mamata Singh R .J. Butcher, N.K. Singh., (2008).," Syntheses and X- Structural Studies of the novel complexes", [Ni(en)2(3-pyt)2] and [Cu(en)2](3- pyt)2 based on 5-(3-pyridyl)-1,3,4-oxadiazole-2-thione, Polyhedron 27, 3151–3159. Hoggarth, (1949), "Compounds Related to Thiosemicarbazi-3-Phenyl-1,2,4- tri azole derivatives" ,J Chem . Soc 2, 113 Cotton F .A. and G. Wilkinson, (1980 ) ," Advance Inorganic Chemistry", 4th Ed. , John Wiley and Sons,Interscienic,NewYork,P.783 Bellamy L.J. (1966)., "The infrared Spectra of complex molecules 3rd ed. Methuen,London. Dogan ,Alev Sakyan Iffet KA+A+C ,Esma.,( 2014)" Synthesis and characterization of amino acid Schiff base complexes", J Solution Chemistry, 33,1539-1547, Satapathy S.and Sahoo B,(1970).,"Salicyl-alazine metal chelates and their IR spectra".,J.Inorg. Nucl . Chem., 12, 2223-2227 William K., (1991) "Organic spectroscopy, 3rd ed.,Macmillan Education Ltd,London,49 54,60- 75 Gamo (1960)., "Infrared spectra of water of crystallization in some inorganic chlorides and Sulfate","Bull .Chem.Soc., 34,760,1430 Chira Bhattacharjee, Pankak Gosurimi, Sankar Neogi and Saptarshi Dhibar . (2010),, "Transition metal complexes of furfuraldohyde and hydrazine hydrate", J.of Sci & Technol., 5(2), 81,87. Tok T. T., O. Ozasik, D. Sarlgol, and A. U. Baran (2015). , "Synthesis and Molecular Modeling Studies of Naproxen-Based Acyl Hydrazone Derivatives.", Turk. J.Chem. 39( 1 ), 54-83 D. Suttan(1998)., " Electronic Spectra ofTransition Metal Complexes", Mc. Grow- Hill Publishing London, pp. 11-21. D. Nicholls(1975) , " The Chemistry of iron, cobalt and nickel", Pergamon Press Oxford, pp.1087. Spina C., M. Pleniceau and C. Tigae( 2008) , "Biologically Active New Fe(II), Co(II), Ni(II)," Chem. Soc.,73 (4), 415-421. Lever ,A.B.P (1968), "Inorganic Electronic Spectroscopy," Amsterdam- London, New -Y ork Soc. Match!(2003-2007)"Crystal impact,phase Identification from Powder Diffraction",version1.6c Licensed to Ankara Uni.Dep.of Geological Engineering site license(c),(http://www. Crystali mpact. com. Stout, C. H L.H. Jensen (1968), "X-ray Structure Determination", Macmillan, New.York. Amira Jihad Al- Shaheen,( 2017)., "Physicochemical Studies and X-ray Powder Diffraction of New Homodinuclear Schiff Base Ccomplexes", International Journal of Enhanced Research in Science ,Technology & Engineering , ISSN :2319-7463 , ISSN: 2319-7463, Vol. 6 Issue 10, October-2017, Impact Factor: 4.059. Aroyo, Mois I. Ulrich Müler and Hans Wondratschek (2007), "Hisiorical Introduction:, International Tables for Crystallography", (Springer) A1 (1:1): 2-5. Doi: 1107/97809.

Year 2019, Volume: 6 , 151 - 161, 25.07.2019

Amerah Jihad Ahmed Shaheen

Abstract

References

Kalagudasi G, Manjula P, Ramesh, V., Rashmisheoy and Sidappa P.''(2007), Transition metal complexes with a new tridentate ligand, 5-_6-(5- mercapto-1,3,4 -oxadiazol -2-yl) pyridin -2-yl-1,3,4-oxadiazole-2- thiol", J. Serb. Chem. Soc. 72, ( 4) 357–366. Almasirad, A; Tabatabai, S.A and Faizi, M; (2004) "Synthesis and biological activity of 1,3,4- oxadiazole derivatives"; Biorg. Med. Chem. Lett; 14, pp. 6057,. Abdel Hamid,M; , (2008)" Synthesis and cyclization reactions with oxadiazole dervatives and their enzymaic activity; Acta. Chim. Slov; 55,. 492-501 Bhat, M. A; Siddiqui, N and Khan, S.A; (2008)." Synthesis of novel 3-(4-Acetyl-5H-methyl-5-substituted phenyl-4,5-dihydro-1,3,4-oxadiazol-2-yl)-2H-chromen -2-ones as potential anticonvulsant agent, Polish. Pharm. Soc; 65 , pp.235-239. Shabbir Akazi (2011)", Synthesis and characterization of a new bidentate ligand 5 -substituted-(2- methyl-5 -nitro-1- imidazomethyl) -1,3,4oxadiazole 2-thione and its metal complexes of Ag(I), Cu(II) and Zn(II)", E -J. of Chemistry 8(S1), S127-S136. Najat A.obaidy,K.K.Abid, Yusra, (2006)." Transition metal complexes of 1,3,4-oxadiazole ligands",National J .of Chem.,24,629-641 H.L. Yale, K. Losee, J. Martins, M. Holsing, F.M. Pery and J. Bernstein, (1953), “Chemotherapy of experimental tuberculosis. VIII. The synthesis of acid hydrazides, Their derivatives and related compounds”, J. Am. Chem. Soc., 75, 1933 Yong Wood(1955) ,"The cyclization of 3- acyl dithiocarbazates ester", J.Am.Chem.Soc.,77. Amira Jihad Al- Shaheen, Tamem A . Al- Muhger, ( 2016) " Synthesis, Spectroscopic and X- ray Powder Diffraction(XRD) of Some Oxadiazole Complexes. " International Journal of Enhanced Research in Science ,Technology & Engineering , ISSN :2319-7463 , Vol.5 issue 6 , June-, p.1339. Amira Jihad Al- Shaheen, Mustafa R.A.Al-Bayati and Amal M.A.Abid Allah.,( 2018) "Synthesis and Characterization of some Metals(II) complexes with 2-(6- methoxy naphthalene-2-yl)Propionic acid(2- hydroxyl benzylidene) hydrazine ligand" . International Journal of Enhanced Research in Science ,Technology & Engineering , ISSN :2319-7463 , ISSN: 2319-7463, Vol 7 Issue 4 april-, Impact Factor: 4.059. Geary W.J( 1971).,"The use of conductivity measurement in organic solvent for Characterization of coordination compounds" , Coord. Chem. Rev., 7, 8 Al- Sabaawi S.A. A .J. Al- Shaheen, (2019)., "Preparation and Physicochemica l Investigation of Manganese (II) complexes with Hydrazone Ligands.,Raf .J .Sc.,Vol .28 ,No.2, Specia l Issue for third Scientific Conference of Chemistry pp.204-210. Mamata Singh R .J. Butcher, N.K. Singh., (2008).," Syntheses and X- Structural Studies of the novel complexes", [Ni(en)2(3-pyt)2] and [Cu(en)2](3- pyt)2 based on 5-(3-pyridyl)-1,3,4-oxadiazole-2-thione, Polyhedron 27, 3151–3159. Hoggarth, (1949), "Compounds Related to Thiosemicarbazi-3-Phenyl-1,2,4- tri azole derivatives" ,J Chem . Soc 2, 113 Cotton F .A. and G. Wilkinson, (1980 ) ," Advance Inorganic Chemistry", 4th Ed. , John Wiley and Sons,Interscienic,NewYork,P.783 Bellamy L.J. (1966)., "The infrared Spectra of complex molecules 3rd ed. Methuen,London. Dogan ,Alev Sakyan Iffet KA+A+C ,Esma.,( 2014)" Synthesis and characterization of amino acid Schiff base complexes", J Solution Chemistry, 33,1539-1547, Satapathy S.and Sahoo B,(1970).,"Salicyl-alazine metal chelates and their IR spectra".,J.Inorg. Nucl . Chem., 12, 2223-2227 William K., (1991) "Organic spectroscopy, 3rd ed.,Macmillan Education Ltd,London,49 54,60- 75 Gamo (1960)., "Infrared spectra of water of crystallization in some inorganic chlorides and Sulfate","Bull .Chem.Soc., 34,760,1430 Chira Bhattacharjee, Pankak Gosurimi, Sankar Neogi and Saptarshi Dhibar . (2010),, "Transition metal complexes of furfuraldohyde and hydrazine hydrate", J.of Sci & Technol., 5(2), 81,87. Tok T. T., O. Ozasik, D. Sarlgol, and A. U. Baran (2015). , "Synthesis and Molecular Modeling Studies of Naproxen-Based Acyl Hydrazone Derivatives.", Turk. J.Chem. 39( 1 ), 54-83 D. Suttan(1998)., " Electronic Spectra ofTransition Metal Complexes", Mc. Grow- Hill Publishing London, pp. 11-21. D. Nicholls(1975) , " The Chemistry of iron, cobalt and nickel", Pergamon Press Oxford, pp.1087. Spina C., M. Pleniceau and C. Tigae( 2008) , "Biologically Active New Fe(II), Co(II), Ni(II)," Chem. Soc.,73 (4), 415-421. Lever ,A.B.P (1968), "Inorganic Electronic Spectroscopy," Amsterdam- London, New -Y ork Soc. Match!(2003-2007)"Crystal impact,phase Identification from Powder Diffraction",version1.6c Licensed to Ankara Uni.Dep.of Geological Engineering site license(c),(http://www. Crystali mpact. com. Stout, C. H L.H. Jensen (1968), "X-ray Structure Determination", Macmillan, New.York. Amira Jihad Al- Shaheen,( 2017)., "Physicochemical Studies and X-ray Powder Diffraction of New Homodinuclear Schiff Base Ccomplexes", International Journal of Enhanced Research in Science ,Technology & Engineering , ISSN :2319-7463 , ISSN: 2319-7463, Vol. 6 Issue 10, October-2017, Impact Factor: 4.059. Aroyo, Mois I. Ulrich Müler and Hans Wondratschek (2007), "Hisiorical Introduction:, International Tables for Crystallography", (Springer) A1 (1:1): 2-5. Doi: 1107/97809.

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Details

Primary Language	English
Subjects	Engineering
Journal Section	Articles
Authors	Amerah Jihad Ahmed Shaheen
Publication Date	July 25, 2019
Published in Issue	Year 2019Volume: 6

Cite

APA	Ahmed Shaheen, A. J. (2019). Synthesis, Investigation and X-Ray Powder Diffraction (XRD) of Some Oxadiazole Complexes. The Eurasia Proceedings of Science Technology Engineering and Mathematics, 6, 151-161.