Research Article
Year 2019,
Volume: 7 , 23 - 32, 24.11.2019
Abstract
References
- https://ar.wikipedia.org/wiki/Hydrazine. E.Fischer,"On aromatic Hydrazine compounds",Berichteder Deutschenchemischen Gesellschaft Zu Berlin,(1875),8,589-594. T.Curtius,"On diamide(Hydrazine)",Berichte der Deutschen Chemischen Gesellschaftzu Berlin,(1887),20,1632-1634. C.A.Lobryde Bruyn,"On the hydrate of Hydrazine",Recueil des Travaux Chimiques des Pays-Bas,(1895),13(8),85-88. D.John Clark,"An informal history of liquid rocket propellants", New Jersey:Rutgers University Press,(1972),p.13. J.P.Schirmann,P.Bourdauducy,"Hydrazine in Ullmann's Encycl -opedia of Industrial Chemistry",Wiley-VCH, Weinheim, (2002), 177. R.Adams,B.K.Brown,"Hydrazine sulfate",Org.Synth. Coll., (1941), 1,307. "Hydrazine:Chemical product info",Chem.industry, (2007),01-08. "Chemistry of petrochemical processes",2nd edition ,Gulf Publishing Company, 2000,p.148. Riegel,Emil Raymond,"Riegel's Handbook of Industrial Chemistry",(1992),p.192. A.F.Holleman, E.Wiberg, "Inorganic Chemistry",Academic press, San Diego,(2001). https://.Chemical Hazard Properties Tableat NOAAgov. Stankovich,"Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide", Carbon.(2007), 45,1558-1565. http://"HYDRAZINE SULFATE".Wikipedia and references in it. "Criteria for a recommended standard: occupation Exposure to Trichloroethylene(73-11025)".CDC-NIOSH Publications and Products,(2016). X.Chen , Y.Xiang , Z.Li , A.Tong , "Sensitive and selective fluorescence determination of trace Hydrazine in aqueous solution utilizing 5-chlorosalicylaldehyde", Anal .Chem. Acta, (2008), 625,41-42. W.Chen, W.Liu, X.J.Liu, Y.Q.Kuang, R.Q.Yu and J.H.Jiang, "A novel fluorescent probe for sensitive detection and imaging of Hydrazine in living cells" Talanta,(2017),162,225-231. H.L.Seifart, W.L.Gent, D.P.Parkin, P.P.Van Jaarsveld and P.R. Donald, "High-performance liquid chromatographic determination of isoniazid, acetylisoniazid and Hydrazine in biological fluids", J.Chro.Bio.Sci.,Appl., (1995),674,269-275. G.Elias,W.F.Bauer,"Hydrazine determination in sludge samples by high-performance liquid chromatography", J.Sep.Sci., (2006), 29(3),460-4. A.Safyavi and A.A.Ensafi,"Kinetic spectrophotometric determination of Hydrazine", Anal.Chim.Acta, (1995),300, 307-311. S.Amlathe, V.K.Gupta," Spectrophotometric determination of Hydrazine in polluted water", Analyst,(1988),113,1481-1483. M.George, K.S.Nagaraja and N.Blalasubramanian," Spectrophotometric determination of Hydrazine", Talanta, (2008) ,75, 27-31. S.Lkeda and H.Satake,"Rapid method for the micro- determination of Hydrazine by amperometric titration with potassium iodate", Anal.Lett,(1987),11,403-413. P.Sahoo,N.Malathi,R.Ananthanarayanon,K.Praveen and N. Murali, "A novel approach for high precision rapid potentime- tric titration :application to Hydrazine assay", Rev.Sci,Inst,(2011) , 82(11),p.102-114. S.Ganesh,F.Khan,MK. Ahmed and SK.Pandey," Potentiometric determination of free acidity in presence of hydrolysable ions and a sequential determination of Hydrazine",Talanta ,(2011), 85(2), 58-63. S. Y. Majeedand W.A. Bashir "Spectrophotometric Determination of Hydrazine Sulphate using Fe(II)-2,2'-Bipyridyl-Application to various water samples
Spectrophotometric Determination of Hydrazine Sulphate using Fe(II)-2,2'-Bipyridyl-Application to Various Water Samples
Abstract
Hydrazine
is an inorganic chemical compound with the chemical structure N2H4.
Hydrazine a colorless flammable liquid compound. Hydrazine is very toxic and
unstable compound, also hydrazine is a strong reducing agent. This compound
easily ignites in the air, generating a large amount of heat and the
composition of nitrogen gas and water. Symptoms of acute (short-term) exposure
to high levels of hydrazine may include irritation of the eyes, nose, throat,
dizziness, headache and nausea. Acute exposure can also damage the liver,
kidneys and central nervous system. Cases of lungs, liver, spleen and thyroid
infection in animals exposed to hydrazine have been reported by inhalation.
Increased lung injury, nasal cavity, and liver tumors were observed in rodents
exposed to hydrazine. This work involves the development of a fast and
sensitive spectrophotometric method for the determination of trace of
hydrazine, the method based on the reduction of ferric ions by hydrazing to
ferrous ions, and finally the later reacts with the reagent (2,2'-bipyridyl) at
60°C to form a stable red-pink complex, this complex is soluble in water and
gave absorption maxima at 523 nm. Beer's law was agreed with range (50-800) µg
of hydrazine per 25 ml (i.e: 2-32 ppm), with a corresponding molar absorptivity
of 5.6×103 l.mol-1.cm-1, Sandell's sensitivity
index of 0.02 µg.cm-2 limit
of quantitation of 0.3 µg/ml, limit of defection 0.1 µg/ml , and finally
average relative standard deviation of +1.25%, depend on the
concentration level. This method had been applied successfully to determination
of hydrazine amount in different samples water (tap water, river water and sea
water).
Keywords
References
- https://ar.wikipedia.org/wiki/Hydrazine. E.Fischer,"On aromatic Hydrazine compounds",Berichteder Deutschenchemischen Gesellschaft Zu Berlin,(1875),8,589-594. T.Curtius,"On diamide(Hydrazine)",Berichte der Deutschen Chemischen Gesellschaftzu Berlin,(1887),20,1632-1634. C.A.Lobryde Bruyn,"On the hydrate of Hydrazine",Recueil des Travaux Chimiques des Pays-Bas,(1895),13(8),85-88. D.John Clark,"An informal history of liquid rocket propellants", New Jersey:Rutgers University Press,(1972),p.13. J.P.Schirmann,P.Bourdauducy,"Hydrazine in Ullmann's Encycl -opedia of Industrial Chemistry",Wiley-VCH, Weinheim, (2002), 177. R.Adams,B.K.Brown,"Hydrazine sulfate",Org.Synth. Coll., (1941), 1,307. "Hydrazine:Chemical product info",Chem.industry, (2007),01-08. "Chemistry of petrochemical processes",2nd edition ,Gulf Publishing Company, 2000,p.148. Riegel,Emil Raymond,"Riegel's Handbook of Industrial Chemistry",(1992),p.192. A.F.Holleman, E.Wiberg, "Inorganic Chemistry",Academic press, San Diego,(2001). https://.Chemical Hazard Properties Tableat NOAAgov. Stankovich,"Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide", Carbon.(2007), 45,1558-1565. http://"HYDRAZINE SULFATE".Wikipedia and references in it. "Criteria for a recommended standard: occupation Exposure to Trichloroethylene(73-11025)".CDC-NIOSH Publications and Products,(2016). X.Chen , Y.Xiang , Z.Li , A.Tong , "Sensitive and selective fluorescence determination of trace Hydrazine in aqueous solution utilizing 5-chlorosalicylaldehyde", Anal .Chem. Acta, (2008), 625,41-42. W.Chen, W.Liu, X.J.Liu, Y.Q.Kuang, R.Q.Yu and J.H.Jiang, "A novel fluorescent probe for sensitive detection and imaging of Hydrazine in living cells" Talanta,(2017),162,225-231. H.L.Seifart, W.L.Gent, D.P.Parkin, P.P.Van Jaarsveld and P.R. Donald, "High-performance liquid chromatographic determination of isoniazid, acetylisoniazid and Hydrazine in biological fluids", J.Chro.Bio.Sci.,Appl., (1995),674,269-275. G.Elias,W.F.Bauer,"Hydrazine determination in sludge samples by high-performance liquid chromatography", J.Sep.Sci., (2006), 29(3),460-4. A.Safyavi and A.A.Ensafi,"Kinetic spectrophotometric determination of Hydrazine", Anal.Chim.Acta, (1995),300, 307-311. S.Amlathe, V.K.Gupta," Spectrophotometric determination of Hydrazine in polluted water", Analyst,(1988),113,1481-1483. M.George, K.S.Nagaraja and N.Blalasubramanian," Spectrophotometric determination of Hydrazine", Talanta, (2008) ,75, 27-31. S.Lkeda and H.Satake,"Rapid method for the micro- determination of Hydrazine by amperometric titration with potassium iodate", Anal.Lett,(1987),11,403-413. P.Sahoo,N.Malathi,R.Ananthanarayanon,K.Praveen and N. Murali, "A novel approach for high precision rapid potentime- tric titration :application to Hydrazine assay", Rev.Sci,Inst,(2011) , 82(11),p.102-114. S.Ganesh,F.Khan,MK. Ahmed and SK.Pandey," Potentiometric determination of free acidity in presence of hydrolysable ions and a sequential determination of Hydrazine",Talanta ,(2011), 85(2), 58-63. S. Y. Majeedand W.A. Bashir "Spectrophotometric Determination of Hydrazine Sulphate using Fe(II)-2,2'-Bipyridyl-Application to various water samples
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Details
| Primary Language | English |
|---|---|
| Subjects | Engineering |
| Journal Section | Articles |
| Authors | |
| Publication Date | November 24, 2019 |
| Published in Issue | Year 2019Volume: 7 |
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