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Year 2019, Volume: 7 , 204 - 211, 24.11.2019

Abstract

References

  • Arinobu, T.; Hattori, H.; Kumazawa, T.; Lee, X.P.; Mizutani, Y.; Katase, T.; Kojima, S.; Omori, T.; Kaneko, R.; Ishii, A.; Seno, H. (2009). High-throughput determination of theophylline and caffeine in human serum by conventional liquid chromatography-mass spectrometry. Forensic. Toxicol.; 27(1), 1-6. Blake, K.; Kamada, A.K. (1996). "Textbook of Therapeutics: Drug and Disease Management". Williams and Wilkins: Baltimore; 6, 651 p. Culzoni, M.J.; De Zan, M.A.; Robles, J.C.; Mantovani, V.E.; Goicoechea, H.C. (2005). Chemometries-assisted uv-spectroscopic strategies for the determination of theophylline insyrups. J. Pharmaceut. Biomed., 39(5),1068-1074. Darmokoesoemo, H.; Khasanah, M.; Sari, N.M.; Kusuma, H.S.; (2017). Analysis of creatinine by potentiometric using electrode carbon paste modified by molecularly imprinted polymer as sensor. Rasayan Journal of Chemistry • 10(2), 450 – 453. Fuyong, J.; Nan, G.; Sheng, Z.; Yuhua, Y. (2018). A Clinical Analysis and Study of 110 Pediatric Cases with Aminophylline Poisoning. Pharmacol. and Clin. Research, 5, 2473-5574. Guo, M.D.; Guo, H.X., Journal of Electroanalytical Chemistry, 585, 28 (2005). Haruta, Y.; Hattori, N.; Kohno, N. (2008). Anti-inflammatory effects and clinical efficacy of theophylline and tulobuterol in mild-to-moderate chronic obstructive pulmonary disease Pulm. Pharmacol. Ther.; 21, 874. Hillson P.J.; and P.P. Birndaun, (1950), Trans. Faraday Soc., 48, 478. Horne, M.M.; Swearingen, P.L.; Fluids, Electrolytes and Acid-Base Balance, 2nd ed., Mosby, St Louis (1993). Igarashi, T.; Iwakawa, S. (2009). Effect of gender on theophylline clearance in japanese pediatric patients. Biol. Pharm. Bull., 32(2), 304-307. Kalyani, L.; Chava, V.; Rao, N. (2017). Development and validation of stability-indicating RP-HPLC method for the simultaneous analysis of Salbutamol, Theophylline and Ambroxol. Saudi J. Med. and Pharm. Sci., 2413-4929. Kanehara, M.; Yokoyama, A.; Tomoda, Y.; Shiota, N.; Iwamoto, H.; Ishikawa, N.; Taooka, Y.; Kawai, M.; Kato, M. (2000). Theophylline for the treatment of bronchial asthma: present status Find. Exp. Clin. Pharmacol., 22(5), 309-320. Kress, M.; Meissner, D.; Kaiser, P.; Hanke, R.; Wood, W.G. (2002). Determination of theophylline by HPLC and GC-IDMS, the effect of chemically similar xanthine derivatives on the specificity of the method and the possibility of paracetamol as interfering substance. Clin. Lab., 48(9-10), 541-551. Minton, N.A.; Henry, J.A. (1996). Acute and chronic human toxicity of theophylline. Human Exp. Toxicol., 15(6), 471-481. Ross, D.P.; Subramanian, S. (1981). Thermodynamics of protein association reactions: forces contributing to stability. Biochemistry, 20, 3096-3102. Sadik, O. A.; Land, W. H.; Wang, J. (2003). Targeting chemical and biological warfare agents at the molecular level. Electroanalysis., 15(14),1149-1159. Skurup, A.; Kristensen, T.; Wennecke G., Clinical Chemistry and Laboratory Medicine, 46(1), 3(2008). Shruti Mouryaa; Ramesh Bodlab; Ravikant Taureanb; Akanksha Sharmab; Simultaneous estimation of xanthine alkaloids (Theophylline, Theobromine and Caffeine): High-Performance Liquid Chromatography International Journal of Drug Regulatory Affairs. 2019; 7(2),35-41. Srdjenovic, B.; Djordjevic-Milic, V.; Grujic, N.; Injac, R.; Lepojevic, C. (2008). Simultaneous HPLC determination of caffeine, theophylline in food, drinks, and herbal products. J. Chromatographic. Sci., 46(2), 144-149. Sujana, K.; Venu, S.; Sravani, K.; Iswarya, P. (2016). simultaneous estimation of salbutamol and theophylline in bulk drugs and marketed formulation using simultaneous equation method. International J. Pharm. Tech. Research CODEN (USA)N; 9, 274-282. Weinberger, M.; Hendeles, L. (1996). Theophylline in asthma. N. Engl, J. Med., 334(21), 1380-1388. Zhou, M.X.; Guan, C.Y.; Chen, G.; Xie, X.Y.; Wu, S.H. (2005). Determination of theophylline concentration in serum by chemiluminescent immunoassay. J. Zhejiang. Univ. Sci. B., 6(12), 1148-1152.

Electrochemical Study of Theophylline-Creatinine Interaction Using Square Wave Voltammetry

Year 2019, Volume: 7 , 204 - 211, 24.11.2019

Abstract

In this work, the interaction between theophylline (TP) and creatinine was studied. A three electrode detection system was used, 2mm diameter glassy carbon electrode as working electrode, 1mm diameter platinum wire as auxillary electrode and Ag/AgCl. saturated KCl as reference electrode. Square wave voltammetric technique (SWV) also used, the voltammogram of theophylline shows a stable well - defined reduction peak at (1.07) V versus Ag/ AgCl Sat. KCl/ in phosphate buffer solution (pH=7) using glassy carbon electrode. The voltammograms were recorded for theophyline with serious addition of creatinine, interaction of theophyline with the sequence addition of creatinine were examined at different temperatures (288, 293, 298, 298, 303, 308 and 310) ºK and the thermodynamics parameters were calculated. The binding constant (K) between theophylene and creatinine was also measured. The results showed that the binding constant (K) decreased with increasing temperature, this is as a result of the negative value of enthalpy change ( -46.6 ) KJ. mol-1 ( exothermic binding ). Negative value of Gibbs energy (-275.338 x 102 _ -36384.961 x102) KJ. mol-1 indicates that the interaction is spontaneous and could be due to van der waals forces or hydrogen bonds effect i. e the low value of Gibbs energy indicates weak interaction between the studied compounds.

References

  • Arinobu, T.; Hattori, H.; Kumazawa, T.; Lee, X.P.; Mizutani, Y.; Katase, T.; Kojima, S.; Omori, T.; Kaneko, R.; Ishii, A.; Seno, H. (2009). High-throughput determination of theophylline and caffeine in human serum by conventional liquid chromatography-mass spectrometry. Forensic. Toxicol.; 27(1), 1-6. Blake, K.; Kamada, A.K. (1996). "Textbook of Therapeutics: Drug and Disease Management". Williams and Wilkins: Baltimore; 6, 651 p. Culzoni, M.J.; De Zan, M.A.; Robles, J.C.; Mantovani, V.E.; Goicoechea, H.C. (2005). Chemometries-assisted uv-spectroscopic strategies for the determination of theophylline insyrups. J. Pharmaceut. Biomed., 39(5),1068-1074. Darmokoesoemo, H.; Khasanah, M.; Sari, N.M.; Kusuma, H.S.; (2017). Analysis of creatinine by potentiometric using electrode carbon paste modified by molecularly imprinted polymer as sensor. Rasayan Journal of Chemistry • 10(2), 450 – 453. Fuyong, J.; Nan, G.; Sheng, Z.; Yuhua, Y. (2018). A Clinical Analysis and Study of 110 Pediatric Cases with Aminophylline Poisoning. Pharmacol. and Clin. Research, 5, 2473-5574. Guo, M.D.; Guo, H.X., Journal of Electroanalytical Chemistry, 585, 28 (2005). Haruta, Y.; Hattori, N.; Kohno, N. (2008). Anti-inflammatory effects and clinical efficacy of theophylline and tulobuterol in mild-to-moderate chronic obstructive pulmonary disease Pulm. Pharmacol. Ther.; 21, 874. Hillson P.J.; and P.P. Birndaun, (1950), Trans. Faraday Soc., 48, 478. Horne, M.M.; Swearingen, P.L.; Fluids, Electrolytes and Acid-Base Balance, 2nd ed., Mosby, St Louis (1993). Igarashi, T.; Iwakawa, S. (2009). Effect of gender on theophylline clearance in japanese pediatric patients. Biol. Pharm. Bull., 32(2), 304-307. Kalyani, L.; Chava, V.; Rao, N. (2017). Development and validation of stability-indicating RP-HPLC method for the simultaneous analysis of Salbutamol, Theophylline and Ambroxol. Saudi J. Med. and Pharm. Sci., 2413-4929. Kanehara, M.; Yokoyama, A.; Tomoda, Y.; Shiota, N.; Iwamoto, H.; Ishikawa, N.; Taooka, Y.; Kawai, M.; Kato, M. (2000). Theophylline for the treatment of bronchial asthma: present status Find. Exp. Clin. Pharmacol., 22(5), 309-320. Kress, M.; Meissner, D.; Kaiser, P.; Hanke, R.; Wood, W.G. (2002). Determination of theophylline by HPLC and GC-IDMS, the effect of chemically similar xanthine derivatives on the specificity of the method and the possibility of paracetamol as interfering substance. Clin. Lab., 48(9-10), 541-551. Minton, N.A.; Henry, J.A. (1996). Acute and chronic human toxicity of theophylline. Human Exp. Toxicol., 15(6), 471-481. Ross, D.P.; Subramanian, S. (1981). Thermodynamics of protein association reactions: forces contributing to stability. Biochemistry, 20, 3096-3102. Sadik, O. A.; Land, W. H.; Wang, J. (2003). Targeting chemical and biological warfare agents at the molecular level. Electroanalysis., 15(14),1149-1159. Skurup, A.; Kristensen, T.; Wennecke G., Clinical Chemistry and Laboratory Medicine, 46(1), 3(2008). Shruti Mouryaa; Ramesh Bodlab; Ravikant Taureanb; Akanksha Sharmab; Simultaneous estimation of xanthine alkaloids (Theophylline, Theobromine and Caffeine): High-Performance Liquid Chromatography International Journal of Drug Regulatory Affairs. 2019; 7(2),35-41. Srdjenovic, B.; Djordjevic-Milic, V.; Grujic, N.; Injac, R.; Lepojevic, C. (2008). Simultaneous HPLC determination of caffeine, theophylline in food, drinks, and herbal products. J. Chromatographic. Sci., 46(2), 144-149. Sujana, K.; Venu, S.; Sravani, K.; Iswarya, P. (2016). simultaneous estimation of salbutamol and theophylline in bulk drugs and marketed formulation using simultaneous equation method. International J. Pharm. Tech. Research CODEN (USA)N; 9, 274-282. Weinberger, M.; Hendeles, L. (1996). Theophylline in asthma. N. Engl, J. Med., 334(21), 1380-1388. Zhou, M.X.; Guan, C.Y.; Chen, G.; Xie, X.Y.; Wu, S.H. (2005). Determination of theophylline concentration in serum by chemiluminescent immunoassay. J. Zhejiang. Univ. Sci. B., 6(12), 1148-1152.
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Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Asmaa M. Al-hasany

Amer Th. Al-taee

Haitham A. Al-wahb

Publication Date November 24, 2019
Published in Issue Year 2019Volume: 7

Cite

APA Al-hasany, A. M., Al-taee, A. T., & Al-wahb, H. A. (2019). Electrochemical Study of Theophylline-Creatinine Interaction Using Square Wave Voltammetry. The Eurasia Proceedings of Science Technology Engineering and Mathematics, 7, 204-211.