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Electrical Conductance Study of Glutamic Acid Complex with [Mn(ΙΙ)] in Different Solvents and Temperatures

Year 2020, Volume: 11, 20 - 28, 31.12.2020

Abstract

The electrical conductivities of glutamic acid complex with [Mn(ΙΙ)] was study in different solvents (water, methanol, ethanol) in the beginning Kohlrausch equations was used to discover types of electrolyte through plot the relation between equivalent conductivity against the square root of molar concentration at different temperature from (288.16 -313.16) kilven. The plot indicate that complex of amino acid was weakly associated in different solvents and temperatures. The molar conductivity of glutamic acid complex measured by processing the obtained data using the conductivity equation of Lee-Wheaton equation to calculation the Equivalent conductance at infinite dilution (Λο) ,The association constant (KA), distance parameter (R), and standard deviation (σΛ).Thermodynamic information from association and examining the nature of the interaction was obtained and calculation of the standard thermodynamic quantities have be measure.A multi parameter curve fitting procedure is used to give the lowest value of curve fitting parameter (σ Λ) between the experimental and calculated values. An iterative numerical method which was found to be very successful has been used to find the minimum( σΛ), show the results of analysis that complex ions were separated by solvent molecules (SSIP).The values of (KA) , (Λο) and (R) differ from solvent to another depending on the interactions in solution.The walden product(Λη) for this complexe have been studied in water, methanol and ethanol.

References

  • Abdel –Rahman, H.A. (2007). An Electrical Conductometric Study of Some Amino Acids and Their Complexes with Some Metals in Aqueous Medium at Different Temperatures . ;M.Sc.Thesis, Mosul University.
  • Al-Allaf, Y.O.; Al-Tamer, M.Y., Abdulfattah, M.N. (2013). Conductometric Studies for Association Reaction of some Amino Acid complexes in Water. Raf. J. Sci., 24(6), pp. 45-60.
  • Al-Healy, F. & Hamed, Y. (2019). Electrochemical and thermodinamic study of tyrosine and its complexes in aqueous solution by conductivity measurement. The Eurasia Proceedings of Science, Technology, Engineering & Mathematics (EPSTEM),7, 48-57.
  • Al-Healy, F. (2020).Conductemetric Study for the Ionic Association of Some Transition Metals Complexes with Some Amino Acids in Different Solvents. (Doctoral dissertation) , University of Mosul (College of Science).
  • Al-Healy,F., & Hameed, Y. (2020). Measurement of the Electrical Conductivity of Equivalent A number of Aspartic Acid Complexes in Different Percentages of Water Mixture with Methanol at 310 Absolute Temperature. Raf. J. Sci., 29(1), 80-94.
  • Chernozhak, T. & Kalugin, O. (2016). Conductivity and interparticle interactions in the solutions of 1-1 electrolytes in propylene carbonat in the wide range of temperatures. Chemistry & Chemical Technologe ,10, No:1, 9-18.
  • Dabbagh, A.M., & Akrawi, B.A. (1992). Kinetics and Electrochemistry. Dar Alkutub for Printing and Publishing, Mosul, pp. 323-405.
  • Doe, H. & Kitagawa, T. (1985). Conductometric Study of Co(II), Ni(II), Cu(II) and Zn(II) Perchlorates in Methanol-Ethylene Glycol Mixtures. Bull. Chem. Soc. Jpn.,58, pp.2975-2980.
  • Eggers, D.F., Gregory, N.W., Halsey, G.D., & Rabinovitch, B.S. (1964). Physical Chemistry. John Wiley and Sons, Inc. New York, 198.
  • Flickinger, M. C. (2010).Encyclopedia of industrial Biotechnology:Bioprocess,Bioseparation, and Cell Technology, Vol.7,Wiley.ISBN.978-471-79930-6.
  • Hummodat, M. Z., & Mustafa, I. (2013). Synthsis and Characterization of Mixed ligand Complexes of Nikal(II) Copper(II) Palladium(II) Platinum(IV) and Gold(III) with Some Amino Acid and Dithiocarbamates or Dithiophosphat in Thetriphenylphosphine Adducts with some of the Nickal(II) Complexes , Ph.D., University of Mosul ,College of Science:53.
  • Lee, W.H. & Wheaton, R.J. (1978). Conductance of symmetrical, unsymmetrical and mixed electrolytes. J. Chem. Soc.,74, 743-766.
  • Lee, W. H., & Wheaton, R. H. (1979). The conductivity of dilute aqueous magnesium chloride at 25◦ C. J. Chem. Soc, 75, 1128.
  • Okubo,Y., Sekiya, H., Namiki,S., Sakamoto,H., Linuma,S., Yamasaki,M., Watanabe,M., Hirose,K., Lion, M. (2010). Imaging extrasynaptic glutamate dynamics in the brain. Proceedings of the National Academy of Scienes, 107(14), 6526–6531.
  • Palmer, W.G. (1954). Experimental Physical Chemistry. Cambridge at the University Press, London, 186.
  • Rabindra, R.P., Radhika, M., & Manjula, P. (2005). Synthesis and characterization of mixed liqand complexes of Zn(II) and Co(II) with Amino Acid: Relevance to Zinc binding sites in Zing fingers . J. Chem. Sci., 117(3), 239-246.
  • Vesna, S., Renato, T., Ivo, T. (2008). Thermodynamics of the association reaction of RbBr in binary mixtures of 2-Butanol and water from 288. 15 to 308.15 K. Acta Chem. Slov., 55, 308-314.
  • Wagner, H. (2012) .Influence of temperature on electrical conductivity of diluted aequas solution. Power Plant Chemistery Journal, Special Edition. 1438-5325
  • William M. H., ) 2016(. Handbook of chemistry and physics, 97th ed.:5-89. CRC Press.
Year 2020, Volume: 11, 20 - 28, 31.12.2020

Abstract

References

  • Abdel –Rahman, H.A. (2007). An Electrical Conductometric Study of Some Amino Acids and Their Complexes with Some Metals in Aqueous Medium at Different Temperatures . ;M.Sc.Thesis, Mosul University.
  • Al-Allaf, Y.O.; Al-Tamer, M.Y., Abdulfattah, M.N. (2013). Conductometric Studies for Association Reaction of some Amino Acid complexes in Water. Raf. J. Sci., 24(6), pp. 45-60.
  • Al-Healy, F. & Hamed, Y. (2019). Electrochemical and thermodinamic study of tyrosine and its complexes in aqueous solution by conductivity measurement. The Eurasia Proceedings of Science, Technology, Engineering & Mathematics (EPSTEM),7, 48-57.
  • Al-Healy, F. (2020).Conductemetric Study for the Ionic Association of Some Transition Metals Complexes with Some Amino Acids in Different Solvents. (Doctoral dissertation) , University of Mosul (College of Science).
  • Al-Healy,F., & Hameed, Y. (2020). Measurement of the Electrical Conductivity of Equivalent A number of Aspartic Acid Complexes in Different Percentages of Water Mixture with Methanol at 310 Absolute Temperature. Raf. J. Sci., 29(1), 80-94.
  • Chernozhak, T. & Kalugin, O. (2016). Conductivity and interparticle interactions in the solutions of 1-1 electrolytes in propylene carbonat in the wide range of temperatures. Chemistry & Chemical Technologe ,10, No:1, 9-18.
  • Dabbagh, A.M., & Akrawi, B.A. (1992). Kinetics and Electrochemistry. Dar Alkutub for Printing and Publishing, Mosul, pp. 323-405.
  • Doe, H. & Kitagawa, T. (1985). Conductometric Study of Co(II), Ni(II), Cu(II) and Zn(II) Perchlorates in Methanol-Ethylene Glycol Mixtures. Bull. Chem. Soc. Jpn.,58, pp.2975-2980.
  • Eggers, D.F., Gregory, N.W., Halsey, G.D., & Rabinovitch, B.S. (1964). Physical Chemistry. John Wiley and Sons, Inc. New York, 198.
  • Flickinger, M. C. (2010).Encyclopedia of industrial Biotechnology:Bioprocess,Bioseparation, and Cell Technology, Vol.7,Wiley.ISBN.978-471-79930-6.
  • Hummodat, M. Z., & Mustafa, I. (2013). Synthsis and Characterization of Mixed ligand Complexes of Nikal(II) Copper(II) Palladium(II) Platinum(IV) and Gold(III) with Some Amino Acid and Dithiocarbamates or Dithiophosphat in Thetriphenylphosphine Adducts with some of the Nickal(II) Complexes , Ph.D., University of Mosul ,College of Science:53.
  • Lee, W.H. & Wheaton, R.J. (1978). Conductance of symmetrical, unsymmetrical and mixed electrolytes. J. Chem. Soc.,74, 743-766.
  • Lee, W. H., & Wheaton, R. H. (1979). The conductivity of dilute aqueous magnesium chloride at 25◦ C. J. Chem. Soc, 75, 1128.
  • Okubo,Y., Sekiya, H., Namiki,S., Sakamoto,H., Linuma,S., Yamasaki,M., Watanabe,M., Hirose,K., Lion, M. (2010). Imaging extrasynaptic glutamate dynamics in the brain. Proceedings of the National Academy of Scienes, 107(14), 6526–6531.
  • Palmer, W.G. (1954). Experimental Physical Chemistry. Cambridge at the University Press, London, 186.
  • Rabindra, R.P., Radhika, M., & Manjula, P. (2005). Synthesis and characterization of mixed liqand complexes of Zn(II) and Co(II) with Amino Acid: Relevance to Zinc binding sites in Zing fingers . J. Chem. Sci., 117(3), 239-246.
  • Vesna, S., Renato, T., Ivo, T. (2008). Thermodynamics of the association reaction of RbBr in binary mixtures of 2-Butanol and water from 288. 15 to 308.15 K. Acta Chem. Slov., 55, 308-314.
  • Wagner, H. (2012) .Influence of temperature on electrical conductivity of diluted aequas solution. Power Plant Chemistery Journal, Special Edition. 1438-5325
  • William M. H., ) 2016(. Handbook of chemistry and physics, 97th ed.:5-89. CRC Press.
There are 19 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Fanar M. Al-healy

Publication Date December 31, 2020
Published in Issue Year 2020Volume: 11

Cite

APA Al-healy, F. M. (2020). Electrical Conductance Study of Glutamic Acid Complex with [Mn(ΙΙ)] in Different Solvents and Temperatures. The Eurasia Proceedings of Science Technology Engineering and Mathematics, 11, 20-28.