Conference Paper
Synthesis and Electrochemical Performance of Spinel Crystal Structured ((FeNiCrMn)1-xCox)3O4 (x=0.1, 0.2, 0.3) High Entropy Oxides
Abstract
High entropy oxides are a new class of materials with a single-phase structure consisting of five or more components. Due to their high structural stability and electrochemical performance, they have attracted a lot of attention in recent years. In this study, high entropy oxides with the composition ((FeNiCrMn)1-xCox)3O4 (x=0.1, 0.2, 0.3) were synthesized using the solid state method and their electrochemical performances as anode material for lithium-ion battery were investigated. Spinel crystal structured of high entropy oxides were characterized by X-ray diffraction (XRD) technique. The electrochemical performance of anodes were evaluated by assembling CR2016 type coin cell. As a result of galvanostatic charge/discharge experiments the initial discharge capacities of ((FeNiCrMn)1-xCox)3O4 (x=0.1, 0.2, 0.3) anodes at a current density of 50 mA g-1 werecalculated as 1993 mA h g-1, 1651 mA h g-1 and 1706 mA h g-1, respectively. Among the synthesized high entropy oxide anodes, the ((FeNiCrMn)0.9Co0.1)3O4 anode shows high initial discharge capacity, while their capacity retention rates at the end of 10th cycle were calculated as 53.9%, 55.1%, 59.7%. This study clearly indicates that the electrochemical performances of high entropy oxide anodes are affected by the Co content.
References
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- Lökçü, E., Toparli, Ç., & Anik, M. (2020). Electrochemical performance of (MgCoNiZn)1-xLixO high-entropy oxides in lithium-ion batteries. ACS Applied Materials & Interfaces, 12, 23860-23866. Long, W., Fang, B., Ignaszak, A., Wu, Z., Wang, Y.J., & Wilkinson, D. (2017).
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Year 2021,
Volume: 16 , 140 - 144, 31.12.2021
Abstract
References
- Chen, H., Qiu, N., Wu, B., Yang, Z., Sun, S., & Wang, Y. (2020). A new spinel high-entropy oxide (Mg0.2Ti0.2Zn0.2Cu0.2Fe0.2)3O4 with fast reaction kinetics and excellent stability as an anode material for lithium ion batteries. RSC Advances, 10(16), 9736–9744. Etacheri, V., Marom, R., Elazari, R., Salitra, G., & Aurbach, D. (2011).
- Challenges in the development of advanced Li-ion batteries: a review. Energy & Environmental Science, 4(9), 3243. Kim, T., Song, W., Son, D.Y., Ono, L. K., & Qi, Y. (2019). Lithium-ion batteries: outlook on present, future, and hybridized technologies. Journal of Materials Chemistry A, 7, 2942-2964.
- Lökçü, E., Toparli, Ç., & Anik, M. (2020). Electrochemical performance of (MgCoNiZn)1-xLixO high-entropy oxides in lithium-ion batteries. ACS Applied Materials & Interfaces, 12, 23860-23866. Long, W., Fang, B., Ignaszak, A., Wu, Z., Wang, Y.J., & Wilkinson, D. (2017).
- Biomass-derived nanostructured carbons and their composites as anode materials for lithium ion batteries. Chemical Society Reviews, 46(23), 7176–7190. Lu, L., Han, X., Li, J., Hua, J., & Ouyang, M. (2013).
- A review on the key issues for lithium-ion battery management in electric vehicles. Journal of Power Sources, 226, 272–288. Nitta, N., Wu, F., Lee, J. T., & Yushin, G. (2015).
- Li-ion battery materials: present and future. Materials Today, 18(5), 252–264.
- Rost, C. M., Sachet, E., Borman, T., Moballegh, A., Dickey, E. C., Hou, D., Jones, J. L., Curtarolo, S., & Maria, J. P. (2015). Entropy-stabilized oxides. Nature Communications, 6, 1−8.
- Sarkar, A., Velasco, L., Wang, D., Wang, Q., Talasila, G., de Biasi, L., Kübel, C., Brezesinski, T., Bhattacharya, S. S., Hahn, H., & Breitung, B. (2018).
- High entropy oxides for reversible energy storage. Nature Communications, 9(3400), 1-9. Shen, X., Liu, H., Cheng, X.B., Yan, C., & Huang, J.-Q. (2018).
- Beyond lithium ion batteries: Higher energy density battery systems based on lithium metal anodes. Energy Storage Materials, 12, 161–175.
- Velàzquez-Martinez, O., Volio, J., Santasalo-Aarnio, A., Reuter, M., & Serna-Guerrero, R. (2019). A critical review of lithium-ion battery recycling processes from a circular economy perspective. Batteries, 5(68), 1-33.
- Zou, Y., & Wang, Y. (2011). Microwave-assisted synthesis of porous nickel oxide nanostructures as anode materials for lithium-ion batteries. Rare Metals, 30, 59–62.
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Details
| Primary Language | English |
|---|---|
| Subjects | Engineering |
| Journal Section | Articles |
| Authors | |
| Publication Date | December 31, 2021 |
| Published in Issue | Year 2021Volume: 16 |
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