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Year 2021, Volume 16, Issue , 140 - 144, 31.12.2021
https://doi.org/10.55549/epstem.1068579

Abstract

References

  • Chen, H., Qiu, N., Wu, B., Yang, Z., Sun, S., & Wang, Y. (2020). A new spinel high-entropy oxide (Mg0.2Ti0.2Zn0.2Cu0.2Fe0.2)3O4 with fast reaction kinetics and excellent stability as an anode material for lithium ion batteries. RSC Advances, 10(16), 9736–9744. Etacheri, V., Marom, R., Elazari, R., Salitra, G., & Aurbach, D. (2011).
  • Challenges in the development of advanced Li-ion batteries: a review. Energy & Environmental Science, 4(9), 3243. Kim, T., Song, W., Son, D.Y., Ono, L. K., & Qi, Y. (2019). Lithium-ion batteries: outlook on present, future, and hybridized technologies. Journal of Materials Chemistry A, 7, 2942-2964.
  • Lökçü, E., Toparli, Ç., & Anik, M. (2020). Electrochemical performance of (MgCoNiZn)1-xLixO high-entropy oxides in lithium-ion batteries. ACS Applied Materials & Interfaces, 12, 23860-23866. Long, W., Fang, B., Ignaszak, A., Wu, Z., Wang, Y.J., & Wilkinson, D. (2017).
  • Biomass-derived nanostructured carbons and their composites as anode materials for lithium ion batteries. Chemical Society Reviews, 46(23), 7176–7190. Lu, L., Han, X., Li, J., Hua, J., & Ouyang, M. (2013).
  • A review on the key issues for lithium-ion battery management in electric vehicles. Journal of Power Sources, 226, 272–288. Nitta, N., Wu, F., Lee, J. T., & Yushin, G. (2015).
  • Li-ion battery materials: present and future. Materials Today, 18(5), 252–264.
  • Rost, C. M., Sachet, E., Borman, T., Moballegh, A., Dickey, E. C., Hou, D., Jones, J. L., Curtarolo, S., & Maria, J. P. (2015). Entropy-stabilized oxides. Nature Communications, 6, 1−8.
  • Sarkar, A., Velasco, L., Wang, D., Wang, Q., Talasila, G., de Biasi, L., Kübel, C., Brezesinski, T., Bhattacharya, S. S., Hahn, H., & Breitung, B. (2018).
  • High entropy oxides for reversible energy storage. Nature Communications, 9(3400), 1-9. Shen, X., Liu, H., Cheng, X.B., Yan, C., & Huang, J.-Q. (2018).
  • Beyond lithium ion batteries: Higher energy density battery systems based on lithium metal anodes. Energy Storage Materials, 12, 161–175.
  • Velàzquez-Martinez, O., Volio, J., Santasalo-Aarnio, A., Reuter, M., & Serna-Guerrero, R. (2019). A critical review of lithium-ion battery recycling processes from a circular economy perspective. Batteries, 5(68), 1-33.
  • Zou, Y., & Wang, Y. (2011). Microwave-assisted synthesis of porous nickel oxide nanostructures as anode materials for lithium-ion batteries. Rare Metals, 30, 59–62.

Synthesis and Electrochemical Performance of Spinel Crystal Structured ((FeNiCrMn)1-xCox)3O4 (x=0.1, 0.2, 0.3) High Entropy Oxides

Year 2021, Volume 16, Issue , 140 - 144, 31.12.2021
https://doi.org/10.55549/epstem.1068579

Abstract

High entropy oxides are a new class of materials with a single-phase structure consisting of five or more components. Due to their high structural stability and electrochemical performance, they have attracted a lot of attention in recent years. In this study, high entropy oxides with the composition ((FeNiCrMn)1-xCox)3O4 (x=0.1, 0.2, 0.3) were synthesized using the solid state method and their electrochemical performances as anode material for lithium-ion battery were investigated. Spinel crystal structured of high entropy oxides were characterized by X-ray diffraction (XRD) technique. The electrochemical performance of anodes were evaluated by assembling CR2016 type coin cell. As a result of galvanostatic charge/discharge experiments the initial discharge capacities of ((FeNiCrMn)1-xCox)3O4 (x=0.1, 0.2, 0.3) anodes at a current density of 50 mA g-1 werecalculated as 1993 mA h g-1, 1651 mA h g-1 and 1706 mA h g-1, respectively. Among the synthesized high entropy oxide anodes, the ((FeNiCrMn)0.9Co0.1)3O4 anode shows high initial discharge capacity, while their capacity retention rates at the end of 10th cycle were calculated as 53.9%, 55.1%, 59.7%. This study clearly indicates that the electrochemical performances of high entropy oxide anodes are affected by the Co content.

References

  • Chen, H., Qiu, N., Wu, B., Yang, Z., Sun, S., & Wang, Y. (2020). A new spinel high-entropy oxide (Mg0.2Ti0.2Zn0.2Cu0.2Fe0.2)3O4 with fast reaction kinetics and excellent stability as an anode material for lithium ion batteries. RSC Advances, 10(16), 9736–9744. Etacheri, V., Marom, R., Elazari, R., Salitra, G., & Aurbach, D. (2011).
  • Challenges in the development of advanced Li-ion batteries: a review. Energy & Environmental Science, 4(9), 3243. Kim, T., Song, W., Son, D.Y., Ono, L. K., & Qi, Y. (2019). Lithium-ion batteries: outlook on present, future, and hybridized technologies. Journal of Materials Chemistry A, 7, 2942-2964.
  • Lökçü, E., Toparli, Ç., & Anik, M. (2020). Electrochemical performance of (MgCoNiZn)1-xLixO high-entropy oxides in lithium-ion batteries. ACS Applied Materials & Interfaces, 12, 23860-23866. Long, W., Fang, B., Ignaszak, A., Wu, Z., Wang, Y.J., & Wilkinson, D. (2017).
  • Biomass-derived nanostructured carbons and their composites as anode materials for lithium ion batteries. Chemical Society Reviews, 46(23), 7176–7190. Lu, L., Han, X., Li, J., Hua, J., & Ouyang, M. (2013).
  • A review on the key issues for lithium-ion battery management in electric vehicles. Journal of Power Sources, 226, 272–288. Nitta, N., Wu, F., Lee, J. T., & Yushin, G. (2015).
  • Li-ion battery materials: present and future. Materials Today, 18(5), 252–264.
  • Rost, C. M., Sachet, E., Borman, T., Moballegh, A., Dickey, E. C., Hou, D., Jones, J. L., Curtarolo, S., & Maria, J. P. (2015). Entropy-stabilized oxides. Nature Communications, 6, 1−8.
  • Sarkar, A., Velasco, L., Wang, D., Wang, Q., Talasila, G., de Biasi, L., Kübel, C., Brezesinski, T., Bhattacharya, S. S., Hahn, H., & Breitung, B. (2018).
  • High entropy oxides for reversible energy storage. Nature Communications, 9(3400), 1-9. Shen, X., Liu, H., Cheng, X.B., Yan, C., & Huang, J.-Q. (2018).
  • Beyond lithium ion batteries: Higher energy density battery systems based on lithium metal anodes. Energy Storage Materials, 12, 161–175.
  • Velàzquez-Martinez, O., Volio, J., Santasalo-Aarnio, A., Reuter, M., & Serna-Guerrero, R. (2019). A critical review of lithium-ion battery recycling processes from a circular economy perspective. Batteries, 5(68), 1-33.
  • Zou, Y., & Wang, Y. (2011). Microwave-assisted synthesis of porous nickel oxide nanostructures as anode materials for lithium-ion batteries. Rare Metals, 30, 59–62.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Meltem CAYIRLI This is me
OSMANGAZI UNIVERSITY
Türkiye


Esra ERDOGAN-ESEN This is me
OSMANGAZI UNIVERSITY
Türkiye


Ersu LOKCU This is me
OSMANGAZI UNIVERSITY
Türkiye


Mustafa ANIK This is me
OSMANGAZI UNIVERSITY
Türkiye

Publication Date December 31, 2021
Published in Issue Year 2021, Volume 16, Issue

Cite

APA Cayırlı, M. , Erdogan-esen, E. , Lokcu, E. & Anık, M. (2021). Synthesis and Electrochemical Performance of Spinel Crystal Structured ((FeNiCrMn)1-xCox)3O4 (x=0.1, 0.2, 0.3) High Entropy Oxides . The Eurasia Proceedings of Science Technology Engineering and Mathematics , 16 , 140-144 . DOI: 10.55549/epstem.1068579